Isotope Separation with Drift Tube, (I)

Isotope Effects, Isotope Separation and Isotope Fractionation

Electrochemical isotope effect and lithium isotope separation.

A large electrochemical isotopic effect is observed upon the electrodeposition of lithium from solutions of propylene carbonate producing isotopically light metal deposits. The magnitude of fractionation is controlled by the applied overpotential and is largest close to equilibrium. Calculated partition function ratios for tetrahedrally coordinated lithium complexes and metallic lithium predict...

Lithium isotope separation with tunable diode lasers.

A laser-isotope-separation study of lithium has been performed with two-step excitation involving UV laser radiation and a visible tunable-diode laser. The method yields a high degree of selectivity by tuning the narrow-linewidth diode laser to the D1 or D2 levels of the lithium atom. Selective laser excitation is simplified by the use of the tunable diode laser and the overall approach benefit...

A split-field drift tube for separation and efficient fragmentation of biomolecular ions.

A new ion mobility instrument that incorporates a low-field region for ion separation and a high-field region for collisional activation is described. In this approach, mixtures of ions are separated based on differences in their mobilities in a approximately 20-cm-long low-field ( approximately 5 V cm(-)(1)) region of a drift tube. As the ions approach the drift tube exit, they are exposed to ...

Laser isotope separation of uranium

A research effort was carried out at the Bhabha Atomic Research Centre (BARC), Mumbai, for developing laser-based techniques for enrichment of natural uranium to reactor-grade (2.5% to 3.0% U), with the potential to be economically scalable to industrial production. Three approaches – two molecular, namely CO2 laser-based approach and UF6-based approach, and one atomic, namely Atomic Vapour Las...